The first observation of four-electron reduction in [60]fullerene-metal cluster self-assembled monolayers (SAMs).

نویسندگان

  • Youn-Jaung Cho
  • Hyunjoon Song
  • Kwangyeol Lee
  • Kyuwon Kim
  • Juhyoun Kwak
  • Sehun Kim
  • Joon T Park
چکیده

Self-assembled monolayers (SAMs) of a mu 3-eta 2:eta 2:eta 2-C60 triosmium cluster complex Os3(CO)8(CN(CH2)3Si(OEt)3)(mu 3-eta 2:eta 2:eta 2-C60) (2) on ITO or Au surface exhibit ideal, well-defined electrochemical responses and remarkable electrochemical stability being reducible up to tetranionic species in their cyclic voltammograms.

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عنوان ژورنال:
  • Chemical communications

دوره 24  شماره 

صفحات  -

تاریخ انتشار 2002